Local elasticity in nonlinear rheology of interacting colloidal glasses revealed by neutron scattering and rheometry
نویسندگان
چکیده
منابع مشابه
Resolving structural modifications of colloidal glasses by combining x-ray scattering and rheology
Glasses have liquid-like structure, but exhibit solid-like properties. A central question concerns the relation between the structure and mechanical properties of glasses, but structural changes remain difficult to resolve. We use a novel combination of rheology and x-ray scattering to resolve structural changes in colloidal glasses and link them directly to their mechanical behavior. By combin...
متن کاملNonlinear rheology of colloidal dispersions.
Colloidal dispersions are commonly encountered in everyday life and represent an important class of complex fluid. Of particular significance for many commercial products and industrial processes is the ability to control and manipulate the macroscopic flow response of a dispersion by tuning the microscopic interactions between the constituents. An important step towards attaining this goal is ...
متن کاملNonlinear elasticity and yielding of nanoparticle glasses.
We employ experiment and theory to explore the nonlinear elasticity and yielding of concentrated suspensions of nanoparticles which interact via purely repulsive forces. These glassy suspensions are found to exhibit high exponent power law or simple exponential dependences of the shear elastic modulus and perturbative yield stress on nanoparticle volume fraction, as well as a monotonic decrease...
متن کاملTheory of nonlinear rheology and yielding of dense colloidal suspensions.
A first-principles approach to the nonlinear flow of dense suspensions is presented which captures shear thinning of colloidal fluids and dynamical yielding of colloidal glasses. The advection of density fluctuations plays a central role, suppressing the caging of particles and speeding up structural relaxation. A mode coupling approach is developed to explore these effects.
متن کاملAnisotropy of small-angle neutron scattering in metallic glasses
2014 SANS in metallic glasses is anisotropic and depends on the orientation of the ribbons. Pd-based melt-spun and Nibased electrochemically deposited glasses exhibit different anisotropies. Both glasses contain scattering centres of the order of 40 nm wide in the ribbon plane. In the melt-spun alloy, the scatterers are very thin along the thickness perpendicular to the substrate. In the deposi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2019
ISSN: 1463-9076,1463-9084
DOI: 10.1039/c8cp05247f